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Preparation and application of a phosphorous free and non-nitrogen scale inhibitor in industrial cooling

Guangqing LIU,Mengwei XUE,Jingyi HUANG,Huchuan WANG,Yuming ZHOU,Qingzhao YAO,Lei LING,Ke CAO,Yahui LIU,Yunyun BU,Yiyi CHEN,Wendao WU,Wei SUN

Frontiers of Environmental Science & Engineering 2015, Volume 9, Issue 3,   Pages 545-553 doi: 10.1007/s11783-014-0657-x

Abstract: A novel environmentally friendly type of calcium carbonate, zinc (II) and iron (III) scale inhibitor Acrylic acid- allylpolyethoxy carboxylate copolymer (AA-APEL) was synthesized. The anti-scale property of the AA-APEL toward CaCO , zinc (II) and iron (III) in the artificial cooling water was studied through static scale inhibition tests. The observation shows that both calcium carbonate, zinc (II) and iron (III) inhibition increase with increasing the dosage of AA-APEL. The effect on formation of CaCO was investigated with combination of scanning electronic microscopy (SEM), transmission electron microscopy (TEM), X-ray powder diffraction (XRD) analysis and fourier transform infrared spectrometer, respectively. The results showed that the AA-APEL copolymer not only influenced calcium carbonate crystal morphology and crystal size but also the crystallinity. The crystallization of CaCO in the absence of inhibitor was rhombohedral calcite crystal, whereas a mixture of calcite with vaterite crystals was found in the presence of the AA-APEL copolymer. Inhibition mechanism is proposed that the interactions between calcium or iron ions and polyethylene glycol (PEG) are the fundamental impetus to restrain the formation of the scale in cooling water systems.

Keywords： phosphorous free     calcium carbonate     stabilize zinc (II)     disperse iron (III)     cooling water    

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Advanced purification and comprehensive utilization of yellow phosphorous off gas

Ping NING,Xiangyu WANG

Frontiers of Environmental Science & Engineering 2015, Volume 9, Issue 2,   Pages 181-189 doi: 10.1007/s11783-014-0698-1

Abstract: Yellow phosphorous is an important raw material in the chemical industry.However, during the production of yellow phosphorous, high concentrations of carbon monoxide and otherPurified yellow phosphorous off gas can be beneficially reused as a raw material in chemical productionIn this paper, the significance of purification and reutilization of yellow phosphorous off gas are exploredcomprehensive reutilization can be an effective solution for heavy pollution resulting from yellow phosphorous

Keywords： yellow phosphorous off gas     purification     comprehensive utilization    

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Phosphorous removal from wastewater by lanthanum modified Y zeolites

Weikang ZHANG, Ye TIAN

Frontiers of Chemical Science and Engineering 2015, Volume 9, Issue 2,   Pages 209-215 doi: 10.1007/s11705-014-1448-4

Abstract: The adsorption capacities of Y zeolite and La (III)-modified Y zeolite were studied. A series of La(III)-modified Y zeolites with different La/Y zeolite mass ratios were characterized by X-ray diffraction, X-ray fluorescence and Brunauer-Emmett-Teller surface area analysis. Batch experiments were conducted to evaluate the effects of various experimental parameters, such as pH, ionic strength, coexisting anions ( , Cl , and ) and temperature, on the phosphate adsorption. The capacity of the La (III)-modified Y zeolite to remove phosphate increased as the La/Y zeolite mass ratio increased and after 4 h, a phosphate removal efficiency of 95% was achieved for a La/Y zeolite mass ratio of 0.10. The equilibrium adsorption isotherm data correlated better to the Langmuir model than the Freundlich model and the data followed a pseudo-second-order kinetic equation.

Keywords： phosphate removal     wastewater     lanthanum     impregnation     Y zeolites    

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Phosphorene: Current status, challenges and opportunities

Anandarup Goswami, Manoj B. Gawande

Frontiers of Chemical Science and Engineering 2019, Volume 13, Issue 2,   Pages 296-309 doi: 10.1007/s11705-018-1783-y

Abstract: materials, the relatively newer addition is phosphorene, which ideally consists of a single layer of black phosphorous

Keywords： phosphorene     black phosphorous     anisotropy     single layer     thermoelectric     chemical vapor deposition     catalysis    

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Cell-free systems in the new age of synthetic biology

Fernando Villarreal,Cheemeng Tan

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 1,   Pages 58-65 doi: 10.1007/s11705-017-1610-x

Abstract: The advent of synthetic biology has ushered in new applications of cell-free transcription-translationThese cell-free systems are reconstituted using cellular proteins, and are amenable to modular controlHere, we discuss the historical advancement of cell-free systems, as well as their new applications inFinally, we present our vision on the future direction of cell-free synthetic biology.

Keywords： cell-free system     application    

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Recent advances in cycloaddition of CO with epoxides: halogen-free catalysis and mechanistic insights

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 12,   Pages 1879-1894 doi: 10.1007/s11705-023-2354-4

Abstract: To address these concerns, the halogen-free cycloaddition of CO2 with epoxides has alwaysIn this review, we systematically discussed the halogen-free catalysis for cycloaddition of CO2freeSpecially, metal oxides as the potential halogen-free catalysts are highlighted due to their flexible

Keywords： carbon dioxide     halogen-free catalysis     cyclic carbonate     mechanistic insight    

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Hollow carbon spheres and their noble metal-free hybrids in catalysis

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 6,   Pages 1380-1407 doi: 10.1007/s11705-021-2097-z

Abstract: Herein, we overview hollow carbon sphere-based materials and their noble metal-free hybrids in catalysiscontrolling pore structure and surface morphology, and then heterogeneous doping as well as their metal-free

Keywords： hollow carbon spheres     functionalization     noble metal-free     catalysis    

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Decontamination of Cr(VI) facilitated formation of persistent free radicals on rice husk derived biochar

Kaikai Zhang, Peng Sun, Yanrong Zhang

Frontiers of Environmental Science & Engineering 2019, Volume 13, Issue 2, doi: 10.1007/s11783-019-1106-7

Abstract:

PFRs were produced on biochar during Cr(VI) decontamination.

PFRs formation on biochar was owing to the oxidization of phenolic-OH by Cr(VI).

Appearance of excessive oxidant led to the consumption of PFRs on biochar.

Biochar charred at high temperature possessed great performance to Cr(VI) removal.

Keywords： Biochar     Persistent free radicals     Phenolic hydroxyl groups     Cr(VI) reduction    

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Thermoresponsive block copolymer supported Pt nanocatalysts for base-free aerobic oxidation of 5-hydroxymethyl

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 6,   Pages 1514-1523 doi: 10.1007/s11705-021-2092-4

Abstract: A base-free catalytic system for the aerobic oxidation of 5-hydroxymethyl-2-furfural was exploited byThe Pt nanocatalysts were well-dispersed and highly active for the base-free oxidation of 5-hydroxymethyl

Keywords： aerobic oxidation     base-free     5-hydroxymethyl-2-furfural     Pt nanoparticle     thermoresponsive block copolymer    

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Influence of the filler materials on flux-free brazing of pure aluminium (1050)

Kirsten BOBZIN, Lidong ZHAO, Thomas SCHLAEFER, Thomas WARDA,

Frontiers of Mechanical Engineering 2010, Volume 5, Issue 1,   Pages 47-51 doi: 10.1007/s11465-009-0079-9

Abstract: Al7Si, Al12Si-4%Cu, and the Al-Si-based filler material A, which was especially developed for flux-free

Keywords： aluminium     flux-free brazing     cold spraying     shear strength    

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New perspectives in free nitrous acid (FNA) uses for sustainable wastewater management

Frontiers of Environmental Science & Engineering 2023, Volume 18, Issue 2, doi: 10.1007/s11783-024-1786-5

Abstract:

● The historical development of free nitrous acid (FNA) technologies

Keywords： Free nitrous acid     Acid-tolerant ammonia oxidizer     In situ generation     Wastewater management    

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Highly selective detection of copper(II) by a “ligand-free” conjugated copolymer in nucleophilic solvents

Weixing Deng, Pengfei Sun, Quli Fan, Lei Zhang, Tsuyoshi Minami

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 1,   Pages 105-111 doi: 10.1007/s11705-019-1791-6

Abstract: cyclohexyl carbamate-attached fluorene- -phenylene copolymer (PFPNCC) and the use of PFPNCC as a “ligand-freehighly selective conjugated polymer-based chemosensors for various target analytes, albeit “ligand-free

Keywords： ligand-free     fluorescent chemosensor     copper     photo-induced electron transfer    

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Ionically Imprinting-Based Copper (Ⅱ) Label-Free Detection for Preventing Hearing Loss Article

Huan Wang, Hui Zhang, Xiaoli Zhang, Hong Chen, Ling Lu, Renjie Chai

Engineering doi: 10.1016/j.eng.2023.09.001

Abstract: solution, IIHBs recognize Cu2+ and exhibit a reflective peak change, thereby achieving label-free

Keywords： Structural color     Microfluidics Ionic imprinting     Label-free detection     Hearing loss    

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Solvent-free mechanochemical mild oxidation method to enhance adsorption properties of chitosan

Frontiers of Environmental Science & Engineering 2021, Volume 15, Issue 6, doi: 10.1007/s11783-021-1416-4

Abstract:

• Solvent-free chitosan oxidation is obtained by rapid mechanochemical

Keywords： Chitosan     High energy ball milling     Mechanochemistry     Oxidation    

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Design approach for single piston hydraulic free piston diesel engines

Wei WU, Shihua YUAN, Jibin HU, Chongbo JING,

Frontiers of Mechanical Engineering 2009, Volume 4, Issue 4,   Pages 371-378 doi: 10.1007/s11465-009-0069-y

Abstract: The operating characteristics of a single piston hydraulic free piston diesel engine differ significantly

Keywords： free piston engine (FPE)     diesel engine     hydraulic equipment     simulation     experiment    

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Title Author Date Type Operation

Preparation and application of a phosphorous free and non-nitrogen scale inhibitor in industrial cooling

Guangqing LIU,Mengwei XUE,Jingyi HUANG,Huchuan WANG,Yuming ZHOU,Qingzhao YAO,Lei LING,Ke CAO,Yahui LIU,Yunyun BU,Yiyi CHEN,Wendao WU,Wei SUN

Journal Article

Advanced purification and comprehensive utilization of yellow phosphorous off gas

Ping NING,Xiangyu WANG

Journal Article

Phosphorous removal from wastewater by lanthanum modified Y zeolites

Weikang ZHANG, Ye TIAN

Journal Article

Phosphorene: Current status, challenges and opportunities

Anandarup Goswami, Manoj B. Gawande

Journal Article

Cell-free systems in the new age of synthetic biology

Fernando Villarreal,Cheemeng Tan

Journal Article

Recent advances in cycloaddition of CO with epoxides: halogen-free catalysis and mechanistic insights

Journal Article

Hollow carbon spheres and their noble metal-free hybrids in catalysis

Journal Article

Decontamination of Cr(VI) facilitated formation of persistent free radicals on rice husk derived biochar

Kaikai Zhang, Peng Sun, Yanrong Zhang

Journal Article

Thermoresponsive block copolymer supported Pt nanocatalysts for base-free aerobic oxidation of 5-hydroxymethyl

Journal Article

Influence of the filler materials on flux-free brazing of pure aluminium (1050)

Kirsten BOBZIN, Lidong ZHAO, Thomas SCHLAEFER, Thomas WARDA,

Journal Article

New perspectives in free nitrous acid (FNA) uses for sustainable wastewater management

Journal Article

Highly selective detection of copper(II) by a “ligand-free” conjugated copolymer in nucleophilic solvents

Weixing Deng, Pengfei Sun, Quli Fan, Lei Zhang, Tsuyoshi Minami

Journal Article

Ionically Imprinting-Based Copper (Ⅱ) Label-Free Detection for Preventing Hearing Loss

Huan Wang, Hui Zhang, Xiaoli Zhang, Hong Chen, Ling Lu, Renjie Chai

Journal Article

Solvent-free mechanochemical mild oxidation method to enhance adsorption properties of chitosan

Journal Article

Design approach for single piston hydraulic free piston diesel engines

Wei WU, Shihua YUAN, Jibin HU, Chongbo JING,

Journal Article